Okay, disable SpeedStep completely and leave SpeedShift enabled for buttery smooth gameplay on Rocket Lake and better Cinebench results at stock.
As for those three VCCs, I wish I was familiar with Asus Z590 BIOS as they sound like they could be something else (I'm using an MSI Z590 currently). VCCSA Load Line Cal(ibration) sounds like an additional setting for the actual VCCSA. And the the other two settings sound like they are for booting voltages, not for later voltages.
So I would explore more, see if you find the actual VCCSA etc tucked away elsewhere, and don't just make note of whether it's on Auto, make a note of the actual voltages which should be displayed alongside.
One thing I don't know if you've mentioned already, and it's important, is whether you have removed the power limits on your board or not? They need removing with Rocket Lake. If unsure you can easily check by seeing how much CPU Package Power is used after a Cinebench R20 run, with HWiNFO64. If it's (quite a lot) more than 125W (as you have an 11900K), then they are removed. Some boards do it by default, I'm not sure if absolutely every Z590 does it. With MSI Z590 it asks you whether you have the boxed cooler or tower style cooler or liquid cooler and removes the power limits accordingly. Your board may have done something similar when you set it up or have them removed by default.